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1.
《能源学会志》2020,93(2):666-678
Coal-fired power plant is the largest anthropogenic mercury source. Active carbon injection technique has been widely used to control the mercury emissions. However, high operation cost limits its development and it is necessary to find other potential mercury sorbents. In this study, raw semi-coke and a series of novel cerium (Ce) modified semi-cokes were synthesized and utilized for removing elemental mercury (Hg0) from simulated flue gas. It is noteworthy that the efficiencies were tested without hydrogen chloride (HCl) in order to evaluate the sorbents efficacy for low-chlorine (Cl) coal. The results show that the modified sorbents exhibited the best performance at 150 °C. The performance of sorbent could be reinforced due to the existence of oxygen (O2), nitric oxide (NO) and HCl. The adverse effect caused by sulfur dioxide (SO2) reduced dramatically after Ce modification. The negative impact of ammonia (NH3) on Hg0 removal in this study could be neglected owing to the tiny concentration of NH3. Raw semi-coke provided sufficient carbon content, which is favorable to mercury adsorption. As Ce loading increased, the carbon structure changed and the crystal of cerium oxide was formed in the modified semi-coke. The mass fraction of cerium oxide on the sorbent was over 4.4% when the concentration of Ce modification solution was higher than 0.2 mol L−1. The redox reaction activity and the oxygen storage ability of Ce3+/Ce4+ gave a huge boost to the performance of modified semi-coke. The addition of Ce also had an impact on the proportion of oxygen species. 相似文献
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Journal of Porous Materials - Based on a new semi-rigid tridentate azole ligand, a porous metal–organic framework (MOF), {[Ni3(tmpa)2(bdc)3]·6DMF}n (1)... 相似文献
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《Journal of the European Ceramic Society》2020,40(4):1186-1190
Two melilite ceramics Sr2AGe2O7 (A = Mg, Zn) with low permittivity were prepared by a solid-state reaction method. The crystal structure and microstructure of the ceramics were characterized by X-ray diffraction, transmission electron microscopy, Raman spectroscopy, and scanning electron microscopy. Both ceramics crystallized in a single melilite structure with a tetragonal space group P-42m (113) and exhibited homogeneous microstructures. Optimum microwave dielectric properties with relative permittivity (εr) of 8.56, quality factor (Q × f) of 28,800 GHz, and temperature coefficient of resonance frequency (τf) of −70.5 ppm/°C were obtained in Sr2MgGe2O7 sintered at 1330 °C. Sr2ZnGe2O7 possessed εr of 8.81, Q × f of 35,700 GHz, and τf of −84.4 ppm/°C when sintered at 1290 °C. Thermal stability of resonance frequency was accessible when the negative τf values of Sr2AGe2O7 were adjusted after the formation of composite ceramics with CaTiO3. 相似文献
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《Ceramics International》2020,46(4):4754-4761
Low density, high stability and strong dielectric loss capacity endow carbon-based nanocomposites with superb microwave dissipation performances. Different from grapheme or carbon nanotubes, the graphitization degrees of carbon-based composites derived from the organic precursor pyrolysis can be accurately regulated by controlling the carbonization temperature. As such, their electromagnetic properties can be easily tuned. In this work, we report the preparation of TiO2/Co/Carbon nanofibers (CNFs) through a combined approach of electrospun and carbonization at different temperatures. The nanofibers with an average diameter of 300 nm were coated by a dense layer of TiO2 and embedded by Co/CoO nanoparticles. The performance evaluation indicated the composite obtained at 700 °C exhibits remarkably strong absorption of −63.2 dB at 9.8 GHz and wide effective absorption bandwidth of 6.4 GHz with a pretty low filling rate of 15 wt%. Further analysis on the electromagnetic behaviors shows that the composite possesses regulable impedance matching characteristic and absorption performances, implying the huge application potential under various demand conditions. 相似文献
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《Journal of the European Ceramic Society》2020,40(4):1111-1118
Highly textured TiB2 ceramics were prepared by slip casting an aqueous suspension in a magnetic field of 9 T, followed by sintering using Field Assisted Sintering Technology (FAST). Particle size refinement by ball milling improved both the degree of texturing and densification of the material (RD > 98 %). The sintered material exhibited a Lotgering orientation factor of 0.90, with the c-axis of TiB2 oriented parallel to the magnetic field and FAST pressing direction. The texturing effect induced by the uniaxial pressing was negligible. The textured TiB2 material exhibited a significant anisotropy in mechanical properties; the values of hardness and indentation elastic modulus measured along directions transverse to the c-axis of TiB2 were 37 % and 13 % higher than the ones measured along the c-axis direction. Moreover, the specific wear rate of a surface of textured TiB2 parallel to the field was one order of magnitude lower than a surface perpendicular to the field. 相似文献
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通过组织观察、力学性能检测和磨损实验,对比研究了洗煤生产过程中齿辊式破碎机的国内4种常用齿板材料的组织和性能。结果表明,进口齿板材料的组织由板条马氏体和6.13%的残余奥氏体组成;高锰钢齿板的组织为单相奥氏体组织;ZG32CrMnSiNi2Mo齿板的组织由贝氏体铁素体板条和13.18%残余奥氏体组成;ZG22CrMnSiNiMo齿板为粒状贝氏体组织,组织中条型M-A岛比例较多,残余奥氏体量为14.9%。940℃淬火+200℃回火后,进口齿板材料具有最优的综合性能,硬度和冲击韧性分别为44.1 HRC和34.5 J;高锰钢齿板水韧处理后平均硬度为216.5 HB,冲击韧度为113.8 J;ZG32CrMnSiNi2Mo齿板900~940℃正火处理后,冲击韧度值略低于进口齿板的供货状态,但硬度高于进口齿板;960~1000℃正火处理后,ZG22CrMnSiNiMo齿板硬度略低于进口齿板材料,冲击韧度略高于进口齿板材料。选取进口齿板材料供货状态为标准,高锰钢齿板材料的相对耐磨性较低,仅为0.76;ZG32CrMnSiNi2Mo齿板材料经900~980℃正火处理后,耐磨性能较好,相对耐磨性为1.19~1.23;ZG22CrMnSiNiMo齿板材料经920~1000℃正火处理,耐磨性能介于进口齿板材料和ZG32CrMnSiNi2Mo齿板材料之间,相对耐磨性为1.10~1.13。 相似文献
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以某9F级燃气-蒸汽联合循环机组余热锅炉为原型,进行了选择性催化还原(SCR)脱硝系统改造设计研究,根据脱硝系统所需氨耗量和烟气参数设计了氨水蒸发系统,根据余热锅炉的具体尺寸和实际运行烟温参数确定了催化剂的布置位置和参数,并采用数值模拟方法研究了改造后余热锅炉脱硝系统的烟气流场。结果表明:对于高位布置的燃气轮机,在扩口段烟道可不设置导流板;采用分区可调的多组一体式氨注射混合器,能在较短距离内加强氨气和NOx的混合;项目改造完成后进行了喷氨优化调整试验,最终脱硝系统出口截面上的NOx分布相对标准偏差从29.6%降至19.6%,氨逃逸量从3.46 ?L/L降至2.89 ?L/L,改善效果明显。 相似文献